Peracetic acid is an environmentally safe and versatile anti-microbial agent and a powerful antioxidant
Category
MSDS
| Porduct Name | Peracetic Acid 30 |
| Part Number | RXSOL-33-1267-001 |
Company Details:
RX MARINE INTERNATIONAL
105, A wing , BSEL , TECH PARK.
VASHI ,NEW BOMBAY 400703 INDIA
Branch : Kandla, Mumbai , Chennai, Vizag, Kolkata, UAE , OMAN , CANADA and KENYA
| Phone | +91 22 20871200 - 1400 |
| Fax | +91 22 27612100 :::AOH :0091 9821214367 |
| mail@rxmarine.com | |
| Website | www.rxmraine.com |
| Product name | Cas No | EC No | Weight | Formula |
| Peracetic Acid 30 | 79-21-0 | 201-186-8 | >= 30 - 50 % | CH3CO3H |
| Signal Word | Danger |
| Hazard Statements | H242 Heating may cause a fire. H301 Toxic if swallowed. H314 Causes severe skin burns and eye damage. H335 May cause respiratory irritation. H410 Very toxic to aquatic life with long lasting effects. |
| Precautionary statements | P210 Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking. P280 Wear protective gloves/ protective clothing/ eye protection/ face protection. P303 + P361 + P353 IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water. P304 + P340 + P310 IF INHALED: Remove person to fresh air and keep comfortable for breathing. Immediately call a POISON CENTER/ doctor. P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P370 + P378 In case of fire: Use dry sand, dry chemical or alcohol-resistant foam to extinguish. P403 + P233 Store in a well-ventilated place. Keep container tightly closed. |
| Classification of the substance or mixture | No data available |
| Supplemental Hazard Statements | No data available |
| Other hazards | This substance/mixture contains no components considered to be either persistent, bioaccumulative and toxic (PBT), or very persistent and very bioaccumulative (vPvB) at levels of 0.1% or higher. |
| General advice | First aiders need to protect themselves. Show this material safety data sheet to the doctor in attendance. |
| If inhaled | After inhalationfresh air. Immediately call in physician. If breathing stops: immediately apply artificial respiration, if necessary also oxygen. |
| Eye Contact | After eye contact: rinse out with plenty of water. Immediately call in ophthalmologist. Remove contact lenses. |
| Swallowed | If swallowed: give water to drink (two glasses at most). Seek medical advice immediately. In exceptional cases only, if medical care is not available within one hour, induce vomiting (only in persons who are wide awake and fully conscious), administer activated charcoal (20 - 40 g in a 10% slurry) and consult a doctor as quickly as possible. Do not attempt to neutralise. |
| Skin Contact | In case of skin contact Take off immediately all contaminated clothing. Rinse skin with water/ shower. Call a physician immediately. |
| Inhalation | No data available |
| Ingestion | No data available |
| Most important symptoms and effects, both acute and delaye | The most important known symptoms and effects are described in the labelling (see section 2.2) and/or in section 11 |
| Indication of any immediate medical attention and special treatment needed | No data available |
| Flammability | No data available |
| Suitable extinguishing media | Water Foam Carbon dioxide (CO2) Dry powder |
| Unsuitable extinguishing media | For this substance/mixture no limitations of extinguishing agents are given. |
| Special hazards arising from the substance or mixture | Carbon oxides Combustible. Fire-promoting. Keep away from combustible materials. Vapors are heavier than air and may spread along floors. Forms explosive mixtures with air on intense heating. Development of hazardous combustion gases or vapours possible in the event of fire |
| Further information | Remove container from danger zone and cool with water. Prevent fire extinguishing water from contaminating surface water or the ground water system. |
|
Hazardous combustion products |
No data available |
| Advice for firefighters | Stay in danger area only with self-contained breathing apparatus. Prevent skin contact by keeping a safe distance or by wearing suitable protective clothing. |
| Protective Equipment | No data available |
| Specific Hazards Arising from the Chemical | No data available |
| Personal precautions, protective equipment and emergency procedures | Advice for non-emergency personnel: Do not breathe vapors, aerosols. Avoid substance contact. Ensure adequate ventilation. Keep away from heat and sources of ignition. Evacuate the danger area, observe emergency procedures, consult an expert. For personal protection see section 8 |
| Spillage | No data available |
| Personal Protection | No data available |
| Enviromental Precaution | Do not let product enter drains. Risk of explosion. |
|
Methods and materials for containment and cleaning |
No data available |
| Reference to other sections | For disposal see section 13. |
| Advice on protection against fire and explosion | Keep away from open flames, hot surfaces and sources of ignition.Take precautionary measures against static discharge. |
| Incompatible materials | No data available |
| Hygiene measures | Immediately change contaminated clothing. Apply preventive skin protection. Wash hands and face after working with substance. For precautions see section 2.2 |
| Advice on safe handling | No data available |
| Conditions for safe storage including any incompatibilities |
No data available |
| Storage conditions | Tightly closed. Keep locked up or in an area accessible only to qualified or authorized persons. Separately or together with other organic peroxides only and away from sources of ignition and heat. Recommended storage temperature see product label. |
| Storage class | Storage class (TRGS 510) 5.2 Organic peroxides and self-reacting hazardous materials |
| Specific end use(s) | Apart from the uses mentioned in section 1.2 no other specific uses are stipulated |
| Advice on general occupational hygiene | No data available |
| Exposure controls | Personal protective equipment |
| Engineering Control | No data available |
| Eye/face protection | Use equipment for eye protection tested and approved under appropriate government standards such as NIOSH (US) or EN 166(EU). Safety glasses |
| Body Protection | Acid-resistant protective clothing |
| Skin protection | This recommendation applies only to the product stated in the safety data sheet, supplied by us and for the designated use. When dissolving in or mixing with other substances and under conditions deviating from those stated in EN374 please contact the supplier of CE-approved gloves (e.g. KCL GmbH, D-36124 Eichenzell, Internet: www.kcl.de). Full contact Material: Chloroprene Minimum layer thickness: 0,65 mm Break through time: 480 min Material tested:KCL 720 Camapren® This recommendation applies only to the product stated in the safety data sheet, supplied by us and for the designated use. When dissolving in or mixing with other substances and under conditions deviating from those stated in EN374 please contact the supplier of CE-approved gloves (e.g. KCL GmbH, D-36124 Eichenzell, Internet: www.kcl.de). Splash contact Material: Latex gloves Minimum layer thickness: 0,6 mm Break through time: 30 min Material tested:Lapren® (KCL 706 / Aldrich Z677558, Size M) |
| Respiratory protection |
Required when vapours/aerosols are generated.Our recommendations on filtering respiratory protection are based on the following standards: DIN EN 143, DIN 14387 and other accompanying standards relating to the used respiratory protection system. Recommended Filter type: Filter type ABEK The entrepeneur has to ensure that maintenance, cleaning and testing of respiratory protective devices are carried out according to the instructions of the producer. These measures have to be properly documented.
|
| Other Protection Measure | No data available |
| Physical state | Liquid |
| Colour | Colorless |
| Odour | Stinging |
| Odor Threshold | No data available |
| pH | ca.1 at 20 °C |
| Melting Point | ca.-37 °C |
| Boiling Point | No data available |
| Flash Point | 62 °C |
| Evaporation Rate | No data available |
| Flammability (solid, gas) | No data available |
| Explosive limits | No data Available |
| Upper/lower flammability or explosive limits | No data available |
| Autoignition temperature | No data available |
| Decomposition temperature | > 60 °C Type D |
| Vapour pressure | ca.14 hPa at 20 °C |
| Viscosity | No data available |
| Density | ca.1,14 g/cm3 at 20 °C |
| Relative Density | 1,950 at 0 °C |
| Specific Gravity | No data available |
| Partition coefficient | No data available |
| Explosive properties | No data available |
| Solubility | at 20 °C soluble |
| Ignition temperature | No data available |
| Particle characteristics | No data available |
| Reactivity | Forms explosive mixtures with air on intense heating. A range from approx. 15 Kelvin below the flash point is to be rated as critical. |
| Chemical stability | stabilised In case of decomposition in closed containers and tubes risk of bursting due to buildup of overpressure. The product is chemically stable under standard ambient conditions (room temperature) |
| Possibilityof hazardous reactions | Risk of explosion with: Heavy metal salts Reducing agents Organic Substances Amines combustible substances Acetic anhydride Strong oxidizing agents Peroxides potassium permanganate perchloric acid phosphorus halides Alkali metals alkali salts Alkaline earth metals Metals metallic oxides Metallic salts nonmetals nonmetallic oxides Aldehydes Ammonia hydrazine and derivatives hydrides Ether anhydrides alkenes organic nitro compounds Brass Impurities Exothermic reaction with: Etheralkalines mineral acids Nitric acid Alcohols chromosulfuric acid halogen-halogen compounds chlorosulfonic acid Tetrahydrofuran metallic chlorides with Risk of ignition or formation of inflammable gases or vapours with: Solvent Hydrocarbons fuming sulfuric acid |
| Conditions to avoid | Heating (explosive decomposition). Strong heating. |
| Incompatible materials |
No data available
|
| Hazardous decomposition products | In the event of fire: see section 5 |
| Acute toxicity | LD50 Oral - Rat - male and female - > 7,5 mg/kg (OECD Test Guideline 401) LC50 Inhalation - Rat - male and female - 4 h - 186 mg/m3 - aerosol Remarks: (ECHA) LD50 Dermal - Rabbit - male and female - > 17,8 mg/kg (US-EPA) LD50 Intravenous - Mouse - male - 212 mg/kg Remarks: (ECHA) |
| Skin corrosion/irritation | Skin - Rabbit Result: Causes severe burns. - 4 h (OECD Test Guideline 404) |
| Serious eye damage/irritation | Eyes - Rabbit Result: Corrosive (US-EPA |
| Respiratory or skin sensitization | Maximization Test - Guinea pigResult: negative (Regulation (EC) No. 440/2008, Annex, B.6) |
| Carcinogenicity | Presumed to have carcinogenic potential for humans |
| Germ cell mutagenicity | Test Type: reverse mutation assay Test system: S. typhimurium Result: negative Test Type: In vitro mammalian cell gene mutation test Test system: Chinese hamster fibroblasts Result: negative Test Type: Chromosome aberration test in vitro Test system: Chinese hamster fibroblasts Result: negative Method: OECD Test Guideline 474 Species: Mouse - male and female - Red blood cells (erythrocytes) Result: negative Method: OECD Test Guideline 486 Species: Rat - male - Liver cells |
| Reproductive toxicity | No data available |
| Specific target organ toxicity - single exposure |
No data available
|
| Additional Information | The substance/mixture does not contain components considered to have endocrine disrupting properties according to REACH Article 57(f) or Commission Delegated regulation (EU) 2017/2100 or Commission Regulation (EU) 2018/605 at levels of 0.1% or higher. Other dangerous properties can not be excluded. Handle in accordance with good industrial hygiene and safety practice |
| Persistence and degradability | No data availalble |
| Toxicity to fish | Semi-static test LC50 - Oncorhynchus mykiss (rainbow trout) - 0,53 mg/l - 96 h (OECD Test Guideline 203) |
| Toxicity to daphnia and other aquatic invertebrates | Static test EC50 - Daphnia magna (Water flea) - 0,73 mg/l - 48 h (OECD Test Guideline 202) |
| Toxicity | No data available |
| Toxicity to bacteria | Static test EC50 - activated sludge - 5,1 mg/l - 3 h (OECD Test Guideline 209) static test NOEC - activated sludge - 16,7 mg/l - 3 h (OECD Test Guideline 209) |
| Toxicity to algae | Static test ErC50 - Pseudokirchneriella subcapitata (green algae) - 0,16 mg/l - 72 h (US-EPA) static test NOEC - Pseudokirchneriella subcapitata (green algae) - 0,061 mg/l - 72 h (US-EPA) |
| Bioaccumulation potential | No data availalble |
| Mobility in soil | No data availalble |
| Results of PBT and vPvB assessment | This substance/mixture contains no components considered to be either persistent, bioaccumulative and toxic (PBT), or very persistent and very bioaccumulative (vPvB) at levels of 0.1% or higher. |
| Endocrine disrupting properties | The substance/mixture does not contain components considered to have endocrine disrupting propertiesaccording to REACH Article 57(f) or Commission Delegated regulation (EU) 2017/2100 or Commission Regulation (EU) 2018/605 at levels of 0.1% or higher. |
| Other adverse effects | Biological effects: Bactericidal effect. Fungicide Discharge into the environment must be avoided |
| Product | Pressurised gas bottle: dispose of only in empty condition! |
| Contaminated packaging | No data available |
| Waste treatment Method | No data available |
| UN number | ADR/RID:3105 | IMDG:3105 |
IATA:1040 |
| UN proper shipping name | ADR/RID:ORGANIC PEROXIDE TYPE D, LIQUID (PEROXYACETIC ACID, TYPE D) | IMDG:ORGANIC PEROXIDE TYPE D, LIQUID (PEROXYACETIC ACID, TYPE D) | IATA:ORGANIC PEROXIDE TYPE D, LIQUID (PEROXYACETIC ACID, TYPE D) |
| Transport hazard class(es) | ADR/RID:5.2 (8) | IMDG:5.2 (8) | IATA:5.2 (8) |
| Packaging group | ADR/RID:- | IMDG:- | IATA:- |
| Environmental hazards | ADR/RID:Yes | IMDG:Yes | IATA:No |
| Special precautions for user | No data available | ||
| Further information | No data available |
| Safety, health and environmental regulations/legislation specific for the substance or mixture | This material safety data sheet complies with the requirements of Regulation (EC) No. 1907/2006. |
| Other regulations | Observe work restrictions regarding maternity protection in accordance to Dir 92/85/EEC or stricter national regulations where applicable. Take note of Dir 94/33/EC on the protection of young people at work |
| Chemical Safety Assessment | A Chemical Safety Assessment was not carried out for this substance. |
| Other Information |
The information above is believed to be accurate and represents the best information currently available to us. However, we make no warranty of merchantability or any other warranty, express or implied, with respect to such information, and weassume no liability resulting from its use. Users should make their own investigations to determine the suitability of the information for their particular purposes. In no event shall be liable for any claims, losses, or damages of any third party or for lost profits or any special, indirect, incidental, consequential or exemplary damages, howsoever arising, even if Rx Marine International has been advised of the possibility of such damages. DISCLAIMER OF LIABILITY :The information in this SDS was obtained from sources which we believe are reliable. However, the information is provided without any warranty, express or implied, regarding its correctness. The conditions or methods of handling, storage, use or disposal of the product are beyond our control and may be beyond our knowledge. For this and other reasons, we do not assume responsibility and expressly disclaim liability for loss, damage or expense arising out of or in any way connected with the handling, storage, use or disposal of the product. This MSDS was prepared and is to be used only for this product. If the product is used as a component in another product, this MSDS information may not be applicable. |