Aqueous oil free industrial cleaner designed as a temporary corrosion protection agent used in spray and immersion processes
Category
MSDS
| Product Name | RXSOL ORG SFN 2448 |
| Part Number | RXSOL-10-3258-025 |
Company Details:....
RX MARINE INTERNATIONAL
105, A wing , BSEL , TECH PARK.
VASHI ,NEW BOMBAY 400703 INDIA
Branch : Kandla, Mumbai , Chennai, Vizag, Kolkata, UAE , OMAN , CANADA and KENYA
| Phone | +91 22 20871200 - 1400 |
| Fax | +91 22 27612100 :::AOH :0091 9821214367 |
| mail@rxmarine.com | |
| Website | www.rxmraine.com |
Mixtures
Declaration of the ingredients according to CLP (EC) No 1272/2008
|
Hazardous components
CAS-No.
EC Number
REACH-Reg No.
|
Concentration | Classification |
Specific Conc. Limits, M
factors and ATEs
|
Add.
Information
|
|
2-aminoethanol
141-43-5
205-483-3
01-2119486455-28
|
20- 40 % |
Acute Tox. 4, Oral, H302
Acute Tox. 4, Dermal, H312
Skin Corr. 1B, H314
Eye Dam. 1, H318
Acute Tox. 4, Inhalation, H332
STOT SE 3, H335
Aquatic Chronic 3, H412
|
STOT SE 3; H335; C >= 5 %
inhalation: ATE = 1,5
mg/l; dust/mist
|
EU OEL |
Classification (CLP)
|
Acute toxicity
H332 Harmful if inhaled.
Route of Exposure: Inhalation
|
Category 4 |
|
Skin corrosion
H314 Causes severe skin burns and eye damage.
|
Category 1B |
|
Serious eye damage
H318 Causes serious eye damage
|
Category 1 |
|
Specific target organ toxicity - single exposure
H335 May cause respiratory irritation.
Target organ: respiratory tract irritation
|
Category 3 |
|
Chronic hazards to the aquatic environment
H412 Harmful to aquatic life with long lasting effects.
|
Category 3 |
Label elements
Label elements (CLP)
| Contains | 2-aminoethanol |
| Signal word | Danger |
| Hazard statement |
H314 Causes severe skin burns and eye damage.
H332 Harmful if inhaled.
H335 May cause respiratory irritation.
H412 Harmful to aquatic life with long lasting effects.
|
|
Precautionary statement
Prevention
|
P260 Do not breathe mist/vapours.
P280 Wear protective gloves/protective clothing/eye protection/face protection.
|
|
Precautionary statement
Response
|
P303+P361+P353 IF ON SKIN (or hair): Take off immediately all contaminated clothing.
Rinse skin with water [or shower].
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove
contact lenses, if present and easy to do. Continue rinsing.
P310 Immediately call a POISON CENTER or doctor.
|
| Other hazards |
None if used properly.
The classification as corrosive H314 category 1 is due to the extreme pH.
Not fulfilling Persistent, Bioaccumulative and Toxic (PBT), very Persistent and very Bioaccumulative (vPvB) criteria.
|
Description of first aid measures
| Inhalation | Fresh air, oxygen supply, warmth; seek specialist medical attention. |
| Skin contact | Immediately rinse with copious amounts of running water (for 10 minutes). Remove contaminated clothes. Put on a bandage with sterile gauze, seek medical attention in hospital. |
| Eye contact | Immediately flush eyes with soft jet of water or eye rinse solution for at least 15 minutes. Hold eyelid wide-open. Seek a doctor/hospital, eye flushing should continue during transportation to a doctor. |
| Ingestion |
Rinse out mouth, drink 1-2 glasses of water, do not induce vomiting.
Immediate medical treatment necessary.
|
| Most important symptoms and effects, both acute and delayed | RESPIRATORY: Irritation, coughing, shortness of breath, chest tightness. |
| Indication of any immediate medical attention and special treatment needed | See section: Description of first aid measures |
Extinguishing media
| Suitable extinguishing media | All common extinguishing agents are suitable. |
| Extinguishing media which must not be used for safety reasons | None known |
| Special hazards arising from the substance or mixture |
Formation of toxic gases is possible during heating or in fires.
|
| Advice for firefighters |
Wear self-contained breathing apparatus.
Wear protective equipment.
|
| Additional information | Cool endangered containers with water spray jet. |
| Personal precautions, protective equipment and emergency procedures | Avoid contact with skin and eyes. |
| Environmental precautions | Do not empty into drains / surface water / ground water. |
| Methods and material for containment and cleaning up |
Remove with liquid-absorbing material (sand, peat, sawdust).
Dispose of contaminated material as waste according to Section 13.
|
| Reference to other sections | See advice in section 8 |
| Precautions for safe handling |
Avoid skin and eye contact.
Ensure that workrooms are adequately ventilated.
When diluting/dissolving always slowly stir the product into water. Do not add product to hot water or hot solutions. Heating
with vigorous, sudden delayed boiling is possible! Scalding hazard!
See advice in section 8
|
| Hygiene measures |
Wash hands before work breaks and after finishing work.
Do not eat, drink or smoke while working.
Wash contaminated clothing before reuse.
The workplace should be equipped with an emergency shower and eye-rinsing facility.
|
| Conditions for safe storage, including any incompatibilities |
Store in sealed original container.
Store at room temperature.
|
| Specific end use(s) | Corrosion Protection Agents for Metals |
Control parameters
Occupational Exposure Limits
| Ingredient [Regulated substance] | ppm | mg/m3 | Value type |
Short term exposure limit
category / Remarks |
Regulatory list |
|
2-Aminoethanol
141-43-5
[2-AMINOETHANOL]
|
3 | 7,6 |
Short Term Exposure
Limit (STEL)
|
Indicative | ECTLV |
|
2-Aminoethanol
141-43-5
[2-AMINOETHANOL]
|
1 | 2,5 |
Time Weighted Average
(TWA)
|
Indicative | ECTLV |
|
2-Aminoethanol
141-43-5
|
|
Short Term Exposure
Classification
|
Category I: substances for
which the localized effect has
an assigned OEL or for
substances with a sensitizing
effect in respiratory passages.
|
TRGS 900 | |
|
2-Aminoethanol
141-43-5 |
0,2 | 0,5 | Exposure limit(s) |
1
If the AGW and BGW values
are complied with, there
should be no risk of
reproductive damage (see
Number 2.7).
|
TRGS 900 |
|
2-Aminoethanol
141-43-5
|
Skin designation | Can be absorbed through the skin. | TRGS 900 |
Predicted No-Effect Concentration (PNEC)
| Name on list | Environmental Compartment | Exposure period | Value | Remarks | |||
| mg/l | ppm | mg/kg | others | ||||
|
2-Aminoethanol
141-43-5
|
aqua (freshwater) | 0,07 mg/l | |||||
|
2-Aminoethanol
141-43-5
|
aqua (marine water) | 0,007 mg/l | |||||
|
2-Aminoethanol
141-43-5
|
aqua (intermittent releases) | 0,028 mg/l | |||||
|
2-Aminoethanol
141-43-5
|
sediment (freshwater) | 0,357 mg/kg | |||||
|
2-Aminoethanol
141-43-5
|
sediment (marine water) | 0,036 mg/kg | |||||
|
2-Aminoethanol
141-43-5
|
Soil | 1,29 mg/kg | |||||
|
2-Aminoethanol
141-43-5
|
sewage treatment plant (STP) | 100 mg/l |
Derived No-Effect Level (DNEL)
| Name on list | Application Area | Route of Exposure | Health Effect | Exposure Time | Value | Remarks |
|
2-Aminoethanol
141-43-5
|
Workers | inhalation |
Long term
exposure -
systemic effects
|
1 mg/m3 | ||
|
2-Aminoethanol
141-43-5
|
Workers | inhalation |
Long term
exposure - local
effects
|
0,51 mg/m3 | ||
|
2-Aminoethanol
141-43-5
|
Workers | dermal |
Long term
exposure -
systemic effects
|
3 mg/kg | ||
|
2-Aminoethanol
141-43-5
|
General population | dermal |
Long term
exposure -
systemic effects
|
1,5 mg/kg | ||
|
2-Aminoethanol
141-43-5
|
General population | oral |
Long term
exposure -
systemic effects
|
1,5 mg/kg | ||
|
2-Aminoethanol
141-43-5
|
General population | inhalation |
Long term
exposure -
systemic effects
|
0,18 mg/m3 | ||
|
2-Aminoethanol
141-43-5
|
General population | inhalation |
Long term
exposure - local
effects
|
0,28 mg/m3 |
| Biological Exposure Indices | None |
| Exposure controls | |
| Engineering controls | Ensure good ventilation/suction at the workplace. |
| Respiratory protection |
In case of aerosol formation, we recommend wearing of appropriate respiratory protection equipment with ABEK P2 filter (EN 14387).
This recommendation should be matched to local conditions.
|
| Hand protection | Chemical-resistant protective gloves (EN 374). Suitable materials for short-term contact or splashes (recommended: at least protection index 2, corresponding to > 30 minutes permeation time as per EN 374): Polychloroprene (CR; >= 1 mm thickness) or natural rubber (NR; >=1 mm thickness) Suitable materials for longer, direct contact (recommended: protection index 6, corresponding to > 480 minutes permeation time as per EN 374): Polychloroprene (CR; >= 1 mm thickness) or natural rubber (NR; >=1 mm thickness) This information is based on literature references and on information provided by glove manufacturers, or is derived by analogy with similar substances. Please note that in practice the working life of chemical-resistant protective gloves may be considerably shorter than the permeation time determined in accordance with EN 374 as a result of the many influencing factors (e.g. temperature). If signs of wear and tear are noticed then the gloves should be replaced. |
| Eye protection |
Goggles which can be tightly sealed.
Protective eye equipment should conform to EN166.
|
| Skin protection |
Protective clothing that covers arms and legs.
Protective clothing should conform to EN 14605 for liquid splashes or to EN 13982 for dusts.
|
| Advices to personal protection equipment |
The information provided on personal protective equipment is for guidance purposes only. A full risk assessment should be conducted prior to using this product to determine the appropriate personal protective equipment to suit local conditions.
Personal protective equipment should conform to the relevant EN standard.
|
| Physical state | Liquid |
| Delivery form | Liquid |
| Colour | Light yellow |
| Odor | Amine-like |
| Melting point | Not applicable, Product is a liquid |
| Solidification temperature | = 0 °C (= 32 °F) |
| Initial boiling point | > 100 °C (> 212 °F)no method |
| Flammability | Non flammable product (flash point is greater than 93°C) |
| Explosive limits | Not applicable, Aqueous solution |
| Flash point | > 100 °C (> 212 °F) |
| Auto-ignition temperature | Not applicable, Aqueous solution |
| Decomposition temperature | Not applicable, Substance/mixture is not self-reactive, no organic peroxide and does not decompose under foreseen conditions of use |
|
pH
(20 °C (68 °F); Conc.: 1,0 % product;
Solvent: Demineralised water)
|
10,70 - 11,30 PH-value, potentiometer |
|
Vapour pressure
(20 °C (68 °F))
|
123 mbar;None |
|
Vapour pressure
(55 °C (131 °F)
|
161 mbar;None |
|
Density
(20 °C (68 °F))
|
1,00 - 1,05 g/cm3 |
|
Relative vapour density:
(20 °C)
|
1 |
| Particle characteristics |
Not applicable
Product is a liquid
|
| Reactivity | Reaction with strong acids. |
| Chemical stability | Stable under recommended storage conditions. |
| Possibility of hazardous reactions | See section reactivity |
| Conditions to avoid | No decomposition if used according to specifications. |
| Incompatible materials |
See section reactivity.
|
| Hazardous decomposition products |
None if used for intended purpose.
In case of fire toxic gases can be released.
|
Information on hazard classes as defined in Regulation (EC) No 1272/2008
Acute oral toxicity
The mixture is classified based on calculation method referring to the classified substances present in the mixture
|
Hazardous substances
CAS-No.
|
Value type | Value | Species | Method |
|
2-aminoethanol
141-43-5
|
LD50 | 1.515 mg/kg | Rat | equivalent or similar to OECD Guideline 401 (Acute Oral Toxicity) |
Acute dermal toxicity
The mixture is classified based on calculation method referring to the classified substances present in the mixture.
|
Hazardous substances
CAS-No.
|
Value type | Value | Species | Method |
|
2-aminoethanol
141-43-5
|
LD50 | 1.025 mg/kg | Rabbit | Not specified |
Acute inhalative toxicity
The mixture is classified based on calculation method referring to the classified substances present in the mixture.
|
Hazardous substances
CAS-No.
|
Value type | Value | Test atmosphere | Exposure time | Species | Method |
|
2-aminoethanol
141-43-5
|
Acute toxicity estimate (ATE) | 1,5 mg/l | dust/mist | Expert judgement | ||
|
2-aminoethanol
141-43-5
|
LC50 | 1 - 5 mg/l | 4 h | Rat | Not specified |
Skin corrosion/irritation
The mixture is classified based on calculation method referring to the classified substances present in the mixture.
|
Hazardous substances
CAS-No.
|
Result | Exposure time | Species | Method |
|
2-aminoethanol
141-43-5
|
corrosive | 4 h | Rabbit | Equivalent or similar to OECD Guideline 404 (Acute Dermal Irritation / Corrosion) |
Serious eye damage/irritation
The mixture is classified based on calculation method referring to the classified substances present in the mixture
|
Hazardous substances
CAS-No.
|
Result | Exposure time | Species | Method |
|
2-aminoethanol
141-43-5
|
corrosive | Rabbit | OECD Guideline 405 (Acute Eye Irritation / Corrosion) |
Respiratory or skin sensitization
The mixture is classified based on threshold limits referring to the classified substances present in the mixture
|
Hazardous substances
CAS-No.
|
Result | Test type | Species | Method |
|
2-aminoethanol
141-43-5
|
Not sensitising | Guinea pig maximisation test | Guinea pig | Not specified |
Germ cell mutagenicity
The mixture is classified based on threshold limits referring to the classified substances present in the mixture.
|
Hazardous substances
CAS-No.
|
Result | Type of study / Route of administration | Metabolic activation / Exposure time | Species | Method |
|
2-aminoethanol
141-43-5
|
Negative | bacterial reverse mutation assay (e.g Ames test) | with and without | Guinea pig | equivalent or similar to OECD Guideline 471 (Bacterial Reverse Mutation Assay) |
|
2-aminoethanol
141-43-5
|
Negative | in vitro mammalian chromosome aberration test | without | equivalent or similar to OECD Guideline 473 (In vitro Mammalian Chromosome Aberration Test) | |
|
2-aminoethanol
141-43-5
|
Negative | mammalian cell gene mutation assay | with and without | OECD Guideline 476 (In vitro Mammalian Cell Gene Mutation Test) | |
|
2-aminoethanol
141-43-5
|
Negative | oral: gavage | mouse | OECD Guideline 474 (Mammalian Erythrocyte Micronucleus Test) |
| Carcinogenicity | No data available. |
Reproductive toxicity
The mixture is classified based on threshold limits referring to the classified substances present in the mixture.
|
Hazardous substances
CAS-No.
|
Result / Value | Test type | Route of application | Species | Method |
|
2-aminoethanol
141-43-5
|
NOAEL P 300 mg/kg
NOAEL F1 1.000 mg/kg
NOAEL F2 1.000 mg/kg
|
Two generation study | oral: feed | Rat |
OECD Guideline 416 (Two Generation Reproduction
Toxicity Study)
|
| STOT-single exposure | No data available. |
STOT-repeated exposure
The mixture is classified based on threshold limits referring to the classified substances present in the mixture.
|
Hazardous substances
CAS-No.
|
Result / Value | Test type | Route of application | Species | Method |
|
2-aminoethanol
141-43-5
|
NOAEL 300 mg/kg | oral: feed | > 75 d daily | Rat | other guideline |
| Aspiration hazard | No data available. |
| Information on other hazards | Not applicable |
| General ecological information |
Do not empty into drains / surface water / ground water.
Locally harmful for aquatic and landliving organisms because of high pH and corrosive properties. |
Toxicity
Toxicity (Fish)
The mixture is classified based on calculation method referring to the classified substances present in the mixture.
|
Hazardous substances
CAS-No.
|
Value type | Value | Exposure time | Species | Method |
|
2-aminoethanol
141-43-5
|
LC50 | 349 mg/l | 96 h | Cyprinus carpio | EU Method C.1 (Acute Toxicity for Fish) |
|
2-aminoethanol
141-43-5
|
NOEC | 1,24 mg/l | 41 h | Oryzias latipes | OECD Guideline 210 (fish early lite stage toxicity test) |
Toxicity (Daphnia)
The mixture is classified based on calculation method referring to the classified substances present in the mixture
|
Hazardous substances
CAS-No.
|
Value type | Value | Exposure time | Species | Method |
|
2-aminoethanol
141-43-5
|
EC50 | 27,04 mg/l | 48 h | Daphnia magna | OECD Guideline 202 (Daphnia sp. Acute Immobilisation Test) |
Chronic toxicity to aquatic invertebrates
The mixture is classified based on calculation method referring to the classified substances present in the mixture.
|
Hazardous substances
CAS-No.
|
Value type | Value | Exposure time | Species | Method |
|
2-aminoethanol
141-43-5
|
NOEC | 0,85 mg/l | 21 d | Daphnia magna | OECD 211 (Daphnia magna, Reproduction Test) |
Toxicity (Algae)
The mixture is classified based on calculation method referring to the classified substances present in the mixture.
|
Hazardous substances
CAS-No.
|
Value type | Value | Exposure time | Species | Method |
|
2-aminoethanol
141-43-5
|
EC50 | 2,8 mg/l | 72 h |
Pseudokirchneriella subcapitata
(reported as Raphidocelis
subcapitata)
|
OECD Guideline 201 (Alga, Growth Inhibition Test) |
|
2-aminoethanol
141-43-5
|
EC10 | 0,7 mg/l | 72 h |
Pseudokirchneriella subcapitata
(reported as Raphidocelis
subcapitata)
|
OECD Guideline 201 (Alga, Growth Inhibition Test) |
| Endocrine disrupting properties | Not applicable |
| Other adverse effects |
If acidic or alkaline products are discharged into wastewater installations care must be taken that the discharged wastewater has a pH in the range pH 6 - 10, as pH variations could cause disorders in wastewater channels and biological sewage treatment plants.
The local discharge regulations take precedence.
|
Waste treatment methods
| Product disposal | In consultation with the responsible local authority, must be subjected to special treatment. |
| Waste code |
EWC/EAK 070608
The valid EWC waste code numbers are source-related. The manufacturer is therefore unable to specify EWC waste codes for the articles or products used in the various sectors. The EWC codes listed are intended as a recommendation for users. We will be happy to advise you.
|
| UN number or ID number | |
| ADR | 2491 |
| RID | 2491 |
| ADN | 2491 |
| IMDG | 2491 |
| IATA | 2491 |
| UN proper shipping name | |
| ADR | ETHANOLAMINE, SOLUTION |
| RID | ETHANOLAMINE, SOLUTION |
| ADN | ETHANOLAMINE, SOLUTION |
| IMDG | ETHANOLAMINE, SOLUTION |
| IATA | Ethanolamine, solution |
| Transport hazard class(es) | |
| ADR | 8 |
| RID | 8 |
| ADN | 8 |
| IMDG | 8 |
| IATA | 8 |
| Packing group | |
| ADR | III |
| RID | III |
| ADN | III |
| IMDG | III |
| IATA | III |
| Environmental hazards | |
| ADR | not applicable |
| RID | not applicable |
| ADN | not applicable |
| IMDG | not applicable |
| IATA | not applicable |
| Special precautions for user | |
| ADR |
not applicable
Tunnel code: (E)
|
| RID | not applicable |
| ADN | not applicable |
| IMDG | not applicable |
| IATA | not applicable |
| Maritime transport in bulk according to IMO instruments | Not applicable |
| Safety, health and environmental regulations/legislation specific for the substance or mixture | |
| Ozone Depleting Substance (ODS) (Regulation (EC) No 1005/2009) |
Not applicable
|
| Prior Informed Consent (PIC) (Regulation (EU) No 649/2012) | Not applicable |
| Persistent organic pollutants (Regulation (EU) 2019/1021) | Not applicable |
| Chemical safety assessment | A chemical safety assessment has not been carried out. |
| National regulations/information (Germany) | |
| WGK |
WGK 1: slightly hazardous to water (Ordinance on facilities for handling substances that are hazardous to water (AwSV) )
Classification according to AwSV, Annex 1 (5.2). |
| Storage class according to TRGS 510 | 8A |
| Other Information |
The information above is believed to be accurate and represents the best information currently available to us. However, we make no warranty of merchantability or any other warranty, express or implied, with respect to such information, and weassume no liability resulting from its use. Users should make their own investigations to determine the suitability of the information for their particular purposes. In no event shall be liable for any claims, losses, or damages of any third party or for lost profits or any special, indirect, incidental, consequential or exemplary damages, howsoever arising, even if Rx Marine International has been advised of the possibility of such damages. DISCLAIMER OF LIABILITY :The information in this SDS was obtained from sources which we believe are reliable. However, the information is provided without any warranty, express or implied, regarding its correctness. The conditions or methods of handling, storage, use or disposal of the product are beyond our control and may be beyond our knowledge. For this and other reasons, we do not assume responsibility and expressly disclaim liability for loss, damage or expense arising out of or in any way connected with the handling, storage, use or disposal of the product. This MSDS was prepared and is to be used only for this product. If the product is used as a component in another product, this MSDS information may not be applicable. |